Down, Michael P.Martinez-Perinan, EmilianoFoster, Christopher W.Lorenzo, EncarnacionSmith, Graham C.Banks, Craig E.2019-06-252019-06-252019-02-10Down, M. P., Martínez-Periñán, E., Foster, C. W., Lorenzo, E., Smith, G. C. & Banks, C. E. (2019). Next-Generation Additive Manufacturing of Complete Standalone Sodium-Ion Energy Storage Architectures. Advanced Energy Materials, 9(11).1614-683210.1002/aenm.201803019http://hdl.handle.net/10034/622373This is the peer reviewed version of the following article: Down, M. P., Martínez-Periñán, E., Foster, C. W., Lorenzo, E., Smith, G. C. & Banks, C. E. (2019). Next-Generation Additive Manufacturing of Complete Standalone Sodium-Ion Energy Storage Architectures. Advanced Energy Materials, 9(11), which has been published in final form at https://doi.org/10.1002/aenm.201803019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-ArchivingThe first entirely AM/3D-printed sodium-ion (full-cell) battery is reported herein, presenting a paradigm shift in the design and prototyping of energy- storage architectures. AM/3D-printing compatible composite materials are developed for the first time, integrating the active materials NaMnO2 and TiO2 within a porous supporting material, before being AM/3D- printed into a proof-of-concept model based upon the basic geometry of commercially existing AA battery designs. The freestanding and completely AM/3D-fabricated device demonstrates a respectable performance of 84.3 mAh g-1 with a current density of 8.43 mA g-1; note that the structure is typically comprised of 80% thermoplastic, but yet, still works and functions as an energy-storage platform. The AM/3D-fabricated device is critically benchmarked against a battery developed using the same active materials, but fabricated via a traditional manufacturing method utilizing an ink-based/doctor-bladed methodology, which is found to exhibit a specific capacity of 98.9 mAh m-2 (116.35 mAh g-1). The fabrication of fully AM/3D-printed energy-storage architectures compares favorably with traditional approaches, with the former providing a new direction in battery manufacturing. This work represents a paradigm shift in the technological and design considerations in battery and energy-storage architecturesenAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/3D printingAdditive ManufacturingAdvanced MaterialsBatteriesEnergyXPSArticle1614-6840Advanced Energy Materials